Non-fluorinated durable water repellent and stain resistant coating

Kaiwen Wang; Yijun Shen; Mingzhang Duan; Tairan Wu; Jiaqi Zhao; Ji Wang

doi:10.54254/2755-2721/7/20230394

Article Information

Received: 1 August 2023

Published: 21 July 2023

DOI: https://doi.org/10.54254/2755-2721/7/20230394

Article Type: Research Article

Cite this article

Wang,K.;Shen,Y.;Duan,M.;Wu,T.;Zhao,J.;Wang,J. (2023). Non-fluorinated durable water repellent and stain resistant coating. Applied and Computational Engineering,7,438-452.

Data availability

The datasets used and/or analyzed during the current study will be available from the authors upon reasonable request.

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Volume Title: ACE Vol.7

Part of Series: Applied and Computational Engineering

ISSN: 2755-2721 (Print) / 2755-273X (Online)

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[1]Guo, Z., & Yang, F. (2018). Surfaces and interfaces of biomimetic superhydrophobic materials. Wiley-VCH.

[2]Staff, S. X. (2016, June 28). Lotus leaf inspires scientists to create world's first self-cleaning metals. Phys.org. Retrieved September 15, 2022, from https://phys.org/news/2016-06-lotus-leaf-scientists-world-self-cleaning.html

[3]Mayser, M. J., Bohn, H. F., Reker, M., & Barthlott, W. (2014). Measuring air layer volumes retained by submerged floating-ferns salvinia and biomimetic superhydrophobic surfaces. Beilstein Journal of Nanotechnology, 5, 812–821. https://doi.org/10.3762/bjnano.5.93

[4]Enviliance ASIA by EnviX, L. (n.d.). PFOA regulations in Asian countries: Enviliance Asia. Enviliacne ASIA. Retrieved September 7, 2022, from https://enviliance.com/regions/others/asia-pfoa

[5]Kota, A. K,. Kwon, G., Tuteja, A.. The design and applications of superomniphobic Surfaces. NPG Asia Materials (2014) 6, e109

[6]Kota, A. K., Choi, W., Tuteja, A. Superomniphobic surfaces: Design and durability. MRS Bull. 38, 383–390 (2013).

[7]T.Young. Philos. Trans. (Royal Soc.) 95, 65-87 (1805).

[8]Wenzel, R. N. Resistance of solid surfaces to wetting by water. Ind. Eng. Chem. 28, 988–994 (1936).

[9]Cassie A, Baxter S. Wettability of porous surfaces. Trans Faraday Soc 1944;40:546–51.

[10]Liang, L., Luo, Z., Mao, Q., et al. Preparation of hydrophobic fabrics and effect of fluorine

[11]monomers on surface properties. Journal of Engineered Fibers and Fabric 2019;14:1-9.

[12]Cheng, Q., Li, M., Zheng, Y., Su, B., Wang, S., & Jiang, L. (2011). Janus interface materials: superhydrophobic air/solid interface and superoleophobic water/solid interface inspired by a lotus leaf. Soft Matter, 7(13), 5948-5951.

[13]Brown, P. S., & Bhushan, B. (2016). Designing bioinspired superoleophobic surfaces. APL Materials, 4(1), 015703

[14]Houde, M., Martin, J. W., Letcher, R. J., Solomon, K. R., & Muir, D. C. (2006). Biological monitoring of polyfluoroalkyl substances: a review. Environmental science & technology, 40(11), 3463-3473.

[15]Sun, Mingxia, et al. "Wetting properties on nanostructured surfaces of cicada wings." Journal of Experimental Biology 212.19 (2009): 3148-3155.

[16]Rakitov Roman and Gorb Stanislav N. 2013Brochosomal coats turn leafhopper (Insecta, Hemiptera, Cicadellidae) integument to superhydrophobic stateProc. R. Soc. B.2802012239120122391

[17]Zhao, H., Park, K. C., & Law, K. Y. (2012). Effect of surface texturing on superoleophobicity, contact angle hysteresis, and “robustness”. Langmuir, 28(42), 14925-14934.

[18]Sekiguchi, Atsushi & Nishino, Tomoki & Aikawa, Masayasu & Matsumoto, Yoko & Minami, Hiroko & Tokumaru, Kazuki & Tsumori, Fujio & Tanigawa, Hiroshi. (2019). The Study of Bile Duct Stent Having Antifouling Properties Using Biomimetics Technique. Journal of Photopolymer Science and Technology. 32. 373-382. 10.2494/photopolymer.32.373.

[19]Autumn, K. Gecko Adhesion: Structure, Function, and Applications. MRS Bulletin 32, 473–478 (2007). https://doi.org/10.1557/mrs2007.80

[20]Isu, N. (2006). Human and environment-friendly materials for dwelling spaces. Journal of Society of Cosmetic Chemists of Japan, 40(3), 187-194.

[21]Xu, Q., Zhang, W., Dong, C., Sreeprasad, T. S., & Xia, Z. (2016). Biomimetic self-cleaning surfaces: synthesis, mechanism and applications. Journal of the Royal Society Interface, 13(122), 20160300.

[22]Wenguo Zhang, Xiaobin Zou, Xiaoli Liu, Zhu Liang, Zhen Ge, Yunjun Luo,Preparation and properties of waterborne polyurethane modified by aminoethylaminopropyl polydimethylsiloxane for fluorine-free water repellents,Progress in Organic Coatings,Volume 139,2020

[23]Sheng, L., Zhang, X., Ge, Z. et al. Preparation and properties of waterborne polyurethane modified by stearyl acrylate for water repellents. J Coat Technol Res 15, 1283–1292 (2018).

[24]Liu Ximeng, Wang Jia, Tan Xiaoqin, Huang Chaokun, Guo Kunwu, Xu Jian, Ni Lijie，Preparation and application of polyacrylate fluorine-free water repellent(in Chinese) Textile Auxiliaries,2021,38(09):17-21.

[25]Zhou Jianhua, Wang Lin, Li Yan, Li Hong Synthesis and application of POSS/organosilicone modified polyacrylate fluoride-free waterproof agent(in Chinese) Fine Chemicals,2021,38(11)

[26]Sharif R, Mohsin M, Sardar S, et al. Synthesis of Nontoxic and Bio Based Oil and Water Repellent Polymers for Cotton Fabrics Using Stearic Acid, Succinic Acid, and Itaconic Acid[J]. Journal of Natural Fibers, 2022: 1-13.

[27]1904, no. 1, 1 May 2021, p. 012010, 10.1088/1742-6596/1904/1/012010. Accessed 7 Aug. 2022.

[28]Lei, Hui, et al. “Fluorine-Free Low Surface Energy Organic Coating for Anti-Stain Applications.” Progress in Organic Coatings, vol. 103, Feb. 2017, pp. 182–192, 10.1016/j.porgcoat.2016.10.036. Accessed 7 Aug. 2022.

[29]Golovin, Kevin, Designing Self-Healing Superhydrophobic Surfaces with Exceptional Mechanical Durability, 2017/03/29, American Chemical Society, doi: 10.1021/acsami.6b15491

[30]Da-Wei Li, Large-scale fabrication of durable and robust super-hydrophobic spray coatings with excellent repairable and anti-corrosion performance,Chemical Engineering Journal,Volume 367,2019,Pages 169-179,ISSN 1385-8947,https://doi.org/10.1016/j.cej.2019.02.093.

[31]Chongjiang Lv, A fluorine-free superhydrophobic PPS composite coating with high thermal stability, wear resistance, corrosion resistance,Progress in Organic Coatings,Volume 110,2017,Pages 47-54,ISSN 0300-9440,https://doi.org/10.1016/j.porgcoat.2017.04.049.

[32]Chongjiang Lv, Fabrication of durable fluorine-free polyphenylene sulfide/silicone resin composite superhydrophobic coating enhanced by carbon nanotubes/graphene fillers,Progress in Organic Coatings,Volume 134,2019,Pages 1-10,ISSN 0300-9440, https://doi.org/10.1016/j.porgcoat.2019.04.042.

[33]Jixi Zhang, Large-Scale Spraying Fabrication of Robust Fluorine-Free Superhydrophobic Coatings Based on Dual-Sized Silica Particles for Effective Antipollution and Strong BuoyancyLangmuir 2021 37 (19), 6042-6051 DOI: 10.1021/acs.langmuir.1c00706

[34]H. Holmquist, Properties, performance and associated hazards of state-of-the-art durable water repellent (DWR) chemistry for textile finishing, Environment International, Volume 91,2016,Pages 251-264,ISSN 0160-4120,https://doi.org/10.1016/j.envint.2016.02.035.

[35]Bangwei Zhang, Physical Fundamentals of Nanomaterials, 1st Edition - February 3, 2018, ISBN: 9780124104174

[36]Keke Shen, Synthesis of a fluorine-free polymeric water-repellent agent for creation of superhydrophobic fabrics, Applied Surface Science, Volume 426, 2017, Pages 694-703, ISSN 0169-4332, https://doi.org/10.1016/j.apsusc.2017.07.245.

[37]Jin S, Park Y, Park CH. Preparation of breathable and superhydrophobic polyurethane electrospun webs with silica nanoparticles. Textile Research Journal. 2016;86(17):1816-1827. doi:10.1177/0040517515617417

[38]Bingbing Xu, Preparation and Properties of Hydrophobically Modified Nano-SiO2 with Hexadecyltrimethoxysilane ACS Omega 2021 6 (14), 9764-9770 DOI: 10.1021/acsomega.1c00381

[39]Qin Zhao, Ambient-curable superhydrophobic fabric coating prepared by water-based non-fluorinated formulation, Materials & Design, Volume 92, 2016, Pages 541-545, ISSN 0264-1275, https://doi.org/10.1016/j.matdes.2015.12.054.

[40]Zhuxing Sun, 3D Graphene Materials: From Understanding to Design and Synthesis Control Chemical Reviews 2020 120 (18), 10336-10453 DOI: 10.1021/acs.chemrev.0c00083

[41]Rui Wang,Large-Diameter Graphene Nanotubes Synthesized Using Ni Nanowire Templates Nano Letters 2010 10 (12), 4844-4850 DOI: 10.1021/nl102445x

[42]Muhammad Zahid, Robust water repellent treatment for woven cotton fabrics with eco-friendly polymers, Chemical Engineering Journal, Volume 319, 2017, Pages 321-332, ISSN 1385-8947, https://doi.org/10.1016/j.cej.2017.03.006.

[43]Jia, S. Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES. Appl. Surf. Sci. 2016, 386, 115–124.

[44]Wang, P.; Chen, M.; Han, H.; Fan, X.; Liu, Q.; Wang, J. Transparent and abrasion-resistant superhydrophobic coating with robust self-cleaning function in either air or oil. J. Mater. Chem. A 2016, 4, 7869–7874.

[45]Wu, L.; Zhang, J.; Li, B.; Wang, A. Mechanical- and oil-durable superhydrophobic polyester materials for selective oil absorption and oil/water separation.

[46]Zhang, Y.; Ge, D.; Yang, S. Spray-coating of superhydrophobic aluminum alloys with enhanced mechanical robustness. J. Colloid Interface Sci. 2014, 423, 101–107

[47]Xiaoge Gregory Zhang, Corrosion and Electrochemistry of Zinc, 1996 ISBN: 978-1-4757-9879-1

[48]Nima Dalir, The Critical Role of Ionic Liquid Crystal on Mg2+ Ion Transport Properties in Magnesium Ion Batteries; Performance and Mechanism Approach, Journal of The Electrochemical Society, Volume 168, Number 7, Nima Dalir et al 2021 J. Electrochem. Soc. 168 070519

[49]Zhu T, Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion. ACS Appl Mater Interfaces. 2017 Mar 22;9(11):10224-10232. doi: 10.1021/acsami.7b00149. Epub 2017 Mar 9. PMID: 28252930.

[50]Iqbal, M.; Dinh, D.K.; Abbas, Q.; Imran, M.; Sattar, H.; Ul Ahmad, A. Controlled Surface Wettability by Plasma Polymer Surface Modification. Surfaces 2019, 2, 349-371. https://doi.org/10.3390/surfaces2020026

[51]Yingke Wang, Fast self-healing superhydrophobic surfaces enabled by biomimetic wax regeneration, Chemical Engineering Journal, Volume 390, 2020, 124311, ISSN 1385-8947, https://doi.org/10.1016/j.cej.2020.124311.