Electrolysis of water for hydrogen production is one of the key technologies for achieving the "dual carbon" goals and the sustainable energy transition. Developing efficient and stable hydrogen evolution reaction (HER) electrocatalysts is the core prerequisite for improving the overall efficiency of water electrolysis hydrogen production. This review systematically summarizes the research progress of HER electrocatalysts driven by nanostructure regulation and electronic structure engineering. This article elaborates on the reaction mechanism and structure-activity relationship of HER and reviews the latest progress of nanomaterial electrocatalyst systems. It systematically summarizes the multi-dimensional control strategies for performance optimization, including defect and vacancy regulation, crystal plane and crystal phase engineering, d-band electronic structure regulation, and design of multiple active sites in synergy. Finally, targeting practical industrial application demands, this work analyzes key challenges including long-term operational stability, structural reconstruction, electrolyzer compatibility, large-scale fabrication of nanomaterials and cost control, and presents a perspective on future research directions.
Research Article
Open Access