Articles in this Volume

Research Article Open Access
Non-Thermal Plasma Catalysis for Flexible Ammonia Production: Linking Reaction Chemistry, Materials, and Reactor Performance
Non-thermal plasma offers a route to synthesize ammonia from nitrogen and hydrogen at a low bulk-gas temperature and near-atmospheric pressure, with the operational flexibility needed for intermittent renewable electricity. Its principal challenge is not ammonia formation alone but the inefficient conversion of electrical energy into recoverable product. This review presents a reactor-centred interpretation of plasma catalysis. It first examines how electron-impact excitation, vibrationally excited nitrogen and radical chemistry establish a non-equilibrium reaction environment. It then considers how packed materials alter electric-field distribution, discharge mode, heat transfer and residence time while also supplying chemical sites for nitrogen adsorption and stepwise hydrogenation. Recent metal, support, defect and porous-material strategies are assessed in terms of these coupled physical and chemical roles. Particular attention is given to ammonia loss by plasma-induced decomposition and to reversible adsorption as a means of separating product formation from product recovery. The review argues that progress requires matched-power controls, complete nitrogen balances, energy yield reporting, transient measurements and long-duration testing. Rather than seeking a universally superior catalyst, future work should co-design the power supply, discharge geometry, accessible surface chemistry and product-removal step for a defined operating window. This paper provides discriminating criteria for delineating the boundary between "physical modification" and "chemical catalysis" in plasma catalysis, while offering a systematic attribution of the origins of energy yield discrepancies reported in the current literature.
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A Review of Solar Energy Multi‑level Synergistic Utilization Systems Based on Spectral Splitting
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Full-spectrum use of solar energy should be achieved efficiently to address the efficiency limitations of single photovoltaic (PV) or photothermal conversion. Spectral splitting technology splits sunlight into various bands and directs them to PV, photothermal and photochemical processes for cascade use. Based on the previous studies, this paper will systematically organize the theoretical foundation of full-spectrum utilization, review spectral splitting methods, discuss integration modes for multi-level synergistic systems, and explore application prospects in building integrated PV (BIPV) and ecological restoration. It also explores the main problems of optical efficiency, system integration and cost control, and puts forward some research directions. Research has shown that spectral-splitting multi-level synergistic systems are emerging as necessary directions for development, but new problems still need to be solved in splitter design, thermal management and life-cycle economic analysis. Future studies should integrate technical performance, economic feasibility, and environmental impacts into a unified life-cycle assessment framework to identify optimal system configurations. Overall, spectral-splitting multi-level synergistic systems represent a promising pathway toward full-spectrum solar energy utilization, but their practical development requires simultaneous improvements in optical components, thermal management, system integration, and economic performance.
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Multi- p arameter E valuation of M ultilayer G ravity F iltration for S ki- R esort S now melt W ater P retreatment and R e us e
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To address the issues of centralized discharge and resource recovery of snowmelt water, a multi-layered gravity filtration system for snowmelt water discharge in ski resorts was developed using filter cotton, activated carbon, quartz sand, and gravel. The experiment examined the impact of filter media combinations, filter bed thickness, filtration time, treated water volume, and inflow rate on treatment performance, using various parameters to measure it, including pH, turbidity, suspended solids (SS), color, and conductivity. The findings have shown that the composite filter bed is effective in improving the particulate matter content and visual water quality of the snowmelt water, reducing turbidity from 238.2 NTU to 17.2 NTU (removal rate of 92.8%) and achieving a suspended solids (SS) removal rate of 65.97%. The rates of turbidity and SS removal were 91.5% and 71.35%, respectively, when the quartz sand layer was raised to 6 cm. The choice to reduce the inflow velocity appropriately to enhance SS retention efficiency was effective, but conductivity was not reduced in equal measure to the indicators of particulate matter. The process is mainly applicable in the removal of particulate pollutants and can be used as a pretreatment unit for the non-portable reuse of snowmelt water in ski resorts.
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Soil Organic Matter Pools Vary Across Management Systems but Weakly Predict Short-Term Nitrogen Cycling
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The dynamics of soil carbon and nitrogen are important for soil fertility and ecosystem functioning, and agricultural management and land use strongly affect them. However, it is still not clear how different management systems change soil organic carbon (SOC) and soil organic nitrogen (SON), or if larger SOC and SON pools go together with more available nitrogen through mineralization and nitrification. The data come from the Kellogg Biological Station Main Cropping System Experiment; this site has SOC and SON measurements for several years and depths, and its nitrogen cycling variables were monitored at 0–25 cm depth. Treatment comparison and linear regression were used to test the differences among systems and the relationships between soil organic matter pools and nitrogen cycling. SOC and SON differed significantly among the treatments; the long successional system had the highest concentrations and the conventional system the lowest. Nitrogen cycling had different treatment patterns, and only SON had a significant positive relationship with net nitrification (R² = 0.16, p = 0.007); the other three regressions were not significant. The analysis relied on one experimental site, and the datasets matched only partly in time; therefore, the results cannot be generalized very far. In general, management had a strong effect on SOC and SON, but these pools by themselves predicted short-term nitrogen cycling only weakly.
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